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Introduction to the behavior of molecules adsorbed on solid surfaces; the structure of surfaces and adsorbate layers. The bonding of molecules to surfaces; adsorbate phase transitions; trapping and sticking of molecules on surfaces. An introduction to surface reactions; kinetics of surface reactions. A review of principles of chemical reactivity; reactivity trends on surfaces; prediction of rates and mechanisms of reactions on metals, semiconductors, and insulators. Course Information: Same as CHEM 586. Prerequisite: CHEM 444.